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For her limit break, Quistis uses Blue Magic. To learn new skills, you need to use a specific item on her from the inventory; the relevant item for each limit break can usually be found on, or mugged from, one of the monsters who uses the attack. You can also gain a lot of the items more easily by using Card-Mod, or other Refinement abilities. Below is a table of blue magic, the items needed to learn it, and an enemy who may drop the item. You can find a Power Generator on the Lunatic Pandora, and you can only refine 100 Curse Spikes into Dark Matter when Siren is at level 100.
Limit
Item
Enemy
Card
LaserBeam
N/A
N/A
N/A
UltraWave
SpiderWeb
Caterchipillar
Caterchipillar
Electrocute
CoralFragment
Blitz, Creeps, Cockatrice
Creep
Level?Death
CurseSpike
Forbidden, Imp, Malboro, Tri-Face
Tri-Face
Degenarator
BlackHole
Gesper, Wendigo
Diablos, Gesper
AquaBreath
Water Crystal
Chimera, Fastitocalon-F, Fastitocalon, Grand Mantis